Beilstein J. Org. Chem.2016,12, 1585–1589, doi:10.3762/bjoc.12.154
experimental conditions and with great economic advantages.
Keywords: deuteration; deuterium atom transfer; radicaland/ororganometallicchemistry; titanocene; Introduction
Deuterium is a stable isotope of hydrogen with 0.015% natural abundance broadly used in organic chemistry, pharmacology, organometallic
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Graphical Abstract
Scheme 1:
Formation of reaction intermediates susceptible of being reduced by Cp2TiCl/Mn/D2O.